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Statistical analysis of C–H activation by oxo complexes supports diverse thermodynamic control over reactivity

Transition metal oxo species are key intermediates for the activation of strong C–H bonds. As such, there has been interest in understanding which structural or electronic parameters of metal oxo complexes determine their reactivity. Factors such as ground state thermodynamics, spin state, steric en...

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Detalles Bibliográficos
Autores principales: Schneider, Joseph E., Goetz, McKenna K., Anderson, John S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179456/
https://www.ncbi.nlm.nih.gov/pubmed/34163690
http://dx.doi.org/10.1039/d0sc06058e