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The electronic structure and deexcitation pathways of an isolated metalloporphyrin ion resolved by metal L-edge spectroscopy

The local electronic structure of the metal-active site and the deexcitation pathways of metalloporphyrins are crucial for numerous applications but difficult to access by commonly employed techniques. Here, we applied near-edge X-ray absorption mass spectrometry and quantum-mechanical restricted ac...

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Detalles Bibliográficos
Autores principales: Schubert, Kaja, Guo, Meiyuan, Atak, Kaan, Dörner, Simon, Bülow, Christine, von Issendorff, Bernd, Klumpp, Stephan, Lau, J. Tobias, Miedema, Piter S., Schlathölter, Thomas, Techert, Simone, Timm, Martin, Wang, Xin, Zamudio-Bayer, Vicente, Schwob, Lucas, Bari, Sadia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179464/
https://www.ncbi.nlm.nih.gov/pubmed/34163667
http://dx.doi.org/10.1039/d0sc06591a