Structural elucidation of a methylenation reagent of esters: synthesis and reactivity of a dinuclear titanium(iii) methylene complex

Transmetallation of a zinc methylene complex [ZnI(tmeda)](2)(μ-CH(2)) with a titanium(iii) chloride [TiCl(3)(tmeda)(thf)] produced a titanium methylene complex. The X-ray diffraction study displayed a dinuclear methylene structure [TiCl(tmeda)](2)(μ-CH(2))(μ-Cl)(2). Treatment of an ester with the ti...

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Detalles Bibliográficos
Autores principales: Kurogi, Takashi, Kuroki, Kaito, Moritani, Shunsuke, Takai, Kazuhiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179466/
https://www.ncbi.nlm.nih.gov/pubmed/34163624
http://dx.doi.org/10.1039/d0sc06366e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179466/
https://www.ncbi.nlm.nih.gov/pubmed/34163624
http://dx.doi.org/10.1039/d0sc06366e

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