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Structural elucidation of a methylenation reagent of esters: synthesis and reactivity of a dinuclear titanium(iii) methylene complex
Transmetallation of a zinc methylene complex [ZnI(tmeda)](2)(μ-CH(2)) with a titanium(iii) chloride [TiCl(3)(tmeda)(thf)] produced a titanium methylene complex. The X-ray diffraction study displayed a dinuclear methylene structure [TiCl(tmeda)](2)(μ-CH(2))(μ-Cl)(2). Treatment of an ester with the ti...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179466/ https://www.ncbi.nlm.nih.gov/pubmed/34163624 http://dx.doi.org/10.1039/d0sc06366e |