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Translational dynamics of a non-degenerate molecular shuttle imbedded in a zirconium metal–organic framework

A new [2]rotaxane molecular shuttle linker based on the binding of a 24-crown-8 ether macrocycle at a benzimidazole recognition site was synthesised. The shuttling dynamics of the linker were studied in solution and the structure confirmed by X-ray crystallography. A multivariate Zr(iv) MOF, UWDM-11...

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Detalles Bibliográficos
Autores principales: Wilson, Benjamin H., Abdulla, Louae M., Schurko, Robert W., Loeb, Stephen J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179482/
https://www.ncbi.nlm.nih.gov/pubmed/34163664
http://dx.doi.org/10.1039/d0sc06837c