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Studying the reactivity of alkyl substituted BODIPYs: first enantioselective addition of BODIPY to MBH carbonates

The first enantioselective addition of alkyl BODIPYs to Morita–Baylis–Hillman (MBH) carbonates is reported. This is the first reported enantioselective methodology using the methylene position of BODIPYs as a nucleophile. The reaction is efficiently catalyzed by cinchona alkaloids, achieving high en...

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Detalles Bibliográficos
Autores principales: Meazza, Marta, Cruz, Carlos M., Ortuño, Ana M., Cuerva, Juan M., Crovetto, Luis, Rios, Ramon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179495/
https://www.ncbi.nlm.nih.gov/pubmed/34163715
http://dx.doi.org/10.1039/d0sc06574a