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Synthesis of azahelicenes through Mallory reaction of imine precursors: corannulene substrates provide an exception to the rule in oxidative photocyclizations of diarylethenes

Typically, the synthesis of phenanthrene-based polycyclic aromatic hydrocarbons relies on the Mallory reaction. In this approach, stilbene (PhCH[double bond, length as m-dash]CHPh)-based precursors undergo an oxidative photocyclization reaction to join the two adjacent aromatic rings into an extende...

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Detalles Bibliográficos
Autores principales: Ghosh, Animesh, Csókás, Dániel, Budanović, Maja, Webster, Richard D., Pápai, Imre, Stuparu, Mihaiela C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179518/
https://www.ncbi.nlm.nih.gov/pubmed/34163668
http://dx.doi.org/10.1039/d0sc06730j