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Modulating the radical reactivity of phenyl radicals with the help of distonic charges: it is all about electrostatic catalysis

This manuscript reports the modulation of H-abstraction reactivity of phenyl radicals by (positive and negative) distonic ions. Specifically, we focus on the origins of this modulating effect: can the charged functional groups truly be described as “extreme forms of electron-withdrawing/donating sub...

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Detalles Bibliográficos
Autores principales: Mondal, Totan, Shaik, Sason, Kenttämaa, Hilkka, Stuyver, Thijs
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179573/
https://www.ncbi.nlm.nih.gov/pubmed/34163733
http://dx.doi.org/10.1039/d0sc07111k