Cargando…
Modulating the radical reactivity of phenyl radicals with the help of distonic charges: it is all about electrostatic catalysis
This manuscript reports the modulation of H-abstraction reactivity of phenyl radicals by (positive and negative) distonic ions. Specifically, we focus on the origins of this modulating effect: can the charged functional groups truly be described as “extreme forms of electron-withdrawing/donating sub...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179573/ https://www.ncbi.nlm.nih.gov/pubmed/34163733 http://dx.doi.org/10.1039/d0sc07111k |