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An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO(2)-to-CO reduction at low overpotential
The [fac-Mn(bpy)(CO)(3)Br] complex is capable of catalyzing the electrochemical reduction of CO(2) to CO with high selectivity, moderate activity and large overpotential. Several attempts have been made to lower the overpotential and to enhance the catalytic activity of this complex by manipulating...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179605/ https://www.ncbi.nlm.nih.gov/pubmed/34168756 http://dx.doi.org/10.1039/d0sc05679k |