Exploiting host–guest chemistry to manipulate magnetic interactions in metallosupramolecular M(4)L(6) tetrahedral cages

Reaction of Ni(OTf)(2) with the bisbidentate quaterpyridine ligand L results in the self-assembly of a tetrahedral, paramagnetic cage [Ni(II)(4)L(6)](8+). By selectively exchanging the bound triflate from [OTf⊂Ni(II)(4)L(6)](OTf)(7) (1), we have been able to prepare a series of host–guest complexes...

Descripción completa

Detalles Bibliográficos
Autores principales: Scott, Aaron J., Vallejo, Julia, Sarkar, Arup, Smythe, Lucy, Regincós Martí, E., Nichol, Gary S., Klooster, Wim T., Coles, Simon J., Murrie, Mark, Rajaraman, Gopalan, Piligkos, Stergios, Lusby, Paul J., Brechin, Euan K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179613/
https://www.ncbi.nlm.nih.gov/pubmed/34168772
http://dx.doi.org/10.1039/d1sc00647a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179613/
https://www.ncbi.nlm.nih.gov/pubmed/34168772
http://dx.doi.org/10.1039/d1sc00647a

Ejemplares similares