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Exploiting host–guest chemistry to manipulate magnetic interactions in metallosupramolecular M(4)L(6) tetrahedral cages

Reaction of Ni(OTf)(2) with the bisbidentate quaterpyridine ligand L results in the self-assembly of a tetrahedral, paramagnetic cage [Ni(II)(4)L(6)](8+). By selectively exchanging the bound triflate from [OTf⊂Ni(II)(4)L(6)](OTf)(7) (1), we have been able to prepare a series of host–guest complexes...

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Detalles Bibliográficos
Autores principales:	Scott, Aaron J., Vallejo, Julia, Sarkar, Arup, Smythe, Lucy, Regincós Martí, E., Nichol, Gary S., Klooster, Wim T., Coles, Simon J., Murrie, Mark, Rajaraman, Gopalan, Piligkos, Stergios, Lusby, Paul J., Brechin, Euan K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179613/ https://www.ncbi.nlm.nih.gov/pubmed/34168772 http://dx.doi.org/10.1039/d1sc00647a

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