Pressure-driven, solvation-directed planar chirality switching of cyclophano-pillar[5]arenes (molecular universal joints)

Planar chiral cyclophanopillar[5]arenes with a fused oligo(oxyethylene) or polymethylene subring (MUJs), existing as an equilibrium mixture of subring-included (in) and -excluded (out) conformers, respond to hydrostatic pressure to exhibit dynamic chiroptical property changes, leading to an unpreced...

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Detalles Bibliográficos
Autores principales: Yao, Jiabin, Mizuno, Hiroaki, Xiao, Chao, Wu, Wanhua, Inoue, Yoshihisa, Yang, Cheng, Fukuhara, Gaku
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179620/
https://www.ncbi.nlm.nih.gov/pubmed/34168749
http://dx.doi.org/10.1039/d0sc06988d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179620/
https://www.ncbi.nlm.nih.gov/pubmed/34168749
http://dx.doi.org/10.1039/d0sc06988d

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