Chemical tuning of spin clock transitions in molecular monomers based on nuclear spin-free Ni(ii)

We report the existence of a sizeable quantum tunnelling splitting between the two lowest electronic spin levels of mononuclear Ni complexes. The level anti-crossing, or magnetic “clock transition”, associated with this gap has been directly monitored by heat capacity experiments. The comparison of...

Descripción completa

Detalles Bibliográficos
Autores principales: Rubín-Osanz, Marcos, Lambert, François, Shao, Feng, Rivière, Eric, Guillot, Régis, Suaud, Nicolas, Guihéry, Nathalie, Zueco, David, Barra, Anne-Laure, Mallah, Talal, Luis, Fernando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179637/
https://www.ncbi.nlm.nih.gov/pubmed/34168771
http://dx.doi.org/10.1039/d0sc05856d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179637/
https://www.ncbi.nlm.nih.gov/pubmed/34168771
http://dx.doi.org/10.1039/d0sc05856d

Ejemplares similares