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Chemical tuning of spin clock transitions in molecular monomers based on nuclear spin-free Ni(ii)
We report the existence of a sizeable quantum tunnelling splitting between the two lowest electronic spin levels of mononuclear Ni complexes. The level anti-crossing, or magnetic “clock transition”, associated with this gap has been directly monitored by heat capacity experiments. The comparison of...
Autores principales: | Rubín-Osanz, Marcos, Lambert, François, Shao, Feng, Rivière, Eric, Guillot, Régis, Suaud, Nicolas, Guihéry, Nathalie, Zueco, David, Barra, Anne-Laure, Mallah, Talal, Luis, Fernando |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179637/ https://www.ncbi.nlm.nih.gov/pubmed/34168771 http://dx.doi.org/10.1039/d0sc05856d |
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