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Towards the rational design of ylide-substituted phosphines for gold(i)-catalysis: from inactive to ppm-level catalysis

The implementation of gold catalysis into large-scale processes suffers from the fact that most reactions still require high catalyst loadings to achieve efficient catalysis thus making upscaling impractical. Here, we report systematic studies on the impact of the substituent in the backbone of ylid...

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Detalles Bibliográficos
Autores principales: Handelmann, Jens, Babu, Chatla Naga, Steinert, Henning, Schwarz, Christopher, Scherpf, Thorsten, Kroll, Alexander, Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179644/
https://www.ncbi.nlm.nih.gov/pubmed/34168748
http://dx.doi.org/10.1039/d1sc00105a