A tellura-Baeyer–Villiger oxidation: one-step transformation of tellurophene into chiral tellurinate lactone

Baeyer–Villiger (BV) oxidation is a fundamental organic reaction, whereas the hetero-BV oxidation is uncharted. Herein, a tellura-BV oxidation is discovered. By oxidizing a tellurophene-embedded and electron-rich polycycle (1) with mCPBA or Oxone, an oxygen atom is inserted into the Te–C bond of the...

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Detalles Bibliográficos
Autores principales: Wang, Shitao, Yan, Chaoxian, Zhao, Wenlong, Liu, Xiaolan, Yuan, Cheng-Shan, Zhang, Hao-Li, Shao, Xiangfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179672/
https://www.ncbi.nlm.nih.gov/pubmed/34168805
http://dx.doi.org/10.1039/d1sc00397f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179672/
https://www.ncbi.nlm.nih.gov/pubmed/34168805
http://dx.doi.org/10.1039/d1sc00397f

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