Formate-driven catalysis and mechanism of an iridium–copper complex for selective aerobic oxidation of aromatic olefins in water

A hetero-dinuclear Ir(III)–Cu(II) complex with two adjacent sites was employed as a catalyst for the aerobic oxidation of aromatic olefins driven by formate in water. An Ir(III)–H intermediate, generated through formate dehydrogenation, was revealed to activate terminal aromatic olefins to afford an...

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Detalles Bibliográficos
Autores principales: Shimoyama, Yoshihiro, Kitagawa, Yasutaka, Ohgomori, Yuji, Kon, Yoshihiro, Hong, Dachao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179673/
https://www.ncbi.nlm.nih.gov/pubmed/34168803
http://dx.doi.org/10.1039/d0sc06634f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179673/
https://www.ncbi.nlm.nih.gov/pubmed/34168803
http://dx.doi.org/10.1039/d0sc06634f

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