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Formate-driven catalysis and mechanism of an iridium–copper complex for selective aerobic oxidation of aromatic olefins in water
A hetero-dinuclear Ir(III)–Cu(II) complex with two adjacent sites was employed as a catalyst for the aerobic oxidation of aromatic olefins driven by formate in water. An Ir(III)–H intermediate, generated through formate dehydrogenation, was revealed to activate terminal aromatic olefins to afford an...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8179673/ https://www.ncbi.nlm.nih.gov/pubmed/34168803 http://dx.doi.org/10.1039/d0sc06634f |