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Selective Manganese-Catalyzed Dimerization and Cross-Coupling of Terminal Alkynes
[Image: see text] Herein, efficient manganese-catalyzed dimerization of terminal alkynes to afford 1,3-enynes is described. This reaction is atom economic, implementing an inexpensive, earth-abundant nonprecious metal catalyst. The precatalyst is the bench-stable alkyl bisphosphine Mn(I) complex fac...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8185884/ https://www.ncbi.nlm.nih.gov/pubmed/34123484 http://dx.doi.org/10.1021/acscatal.1c01137 |