A dynamic picture of the halolactonization reaction through a combination of ab initio metadynamics and experimental investigations

The halolactonization reaction is one of the most common electrophilic addition reactions to alkenes. The mechanism is generally viewed as a two-step pathway, which involves the formation of an ionic intermediate, in most cases a haliranium ion. Recently, an alternative concerted mechanism was propo...

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Detalles Bibliográficos
Autores principales: Van Lommel, Ruben, Bock, Jonathan, Daniliuc, Constantin G., Hennecke, Ulrich, De Proft, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8188468/
https://www.ncbi.nlm.nih.gov/pubmed/34168827
http://dx.doi.org/10.1039/d1sc01014j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8188468/
https://www.ncbi.nlm.nih.gov/pubmed/34168827
http://dx.doi.org/10.1039/d1sc01014j

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