Asymmetric hydrogenation of exocyclic γ,δ-unsaturated β-ketoesters to functionalized chiral allylic alcohols via dynamic kinetic resolution

An iridium catalyzed asymmetric hydrogenation of racemic exocyclic γ,δ-unsaturated β-ketoesters via dynamic kinetic resolution to functionalized chiral allylic alcohols was developed. With the chiral spiro iridium catalysts Ir-SpiroPAP, a series of racemic exocyclic γ,δ-unsaturated β-ketoesters bear...

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Detalles Bibliográficos
Autores principales: Bin, Huai-Yu, Cheng, Li, Wu, Xiong, Zhu, Chang-Liang, Yang, Xiao-Hui, Xie, Jian-Hua, Zhou, Qi-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8188505/
https://www.ncbi.nlm.nih.gov/pubmed/34168833
http://dx.doi.org/10.1039/d1sc02044g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8188505/
https://www.ncbi.nlm.nih.gov/pubmed/34168833
http://dx.doi.org/10.1039/d1sc02044g

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