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Rare-Earth–Silyl ate-Complexes Opening a Door to Selective Manipulations
[Image: see text] The reactions of a number of rare-earth (RE) trichlorides and an oligosilanylene diide containing a siloxane unit in the backbone in DME are described. The formed products of the type [(DME)(4)·K][(DME)·RE(Cl)(2){Si(SiMe(3))(2)SiMe(2)}(2)O] (RE = Y, La, Ce, Pr, Sm, Tb, Dy, and Er)...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8188526/ https://www.ncbi.nlm.nih.gov/pubmed/34033463 http://dx.doi.org/10.1021/acs.inorgchem.1c00904 |