Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity

Doubly base-stabilised cyano- and isothiocyanatoborylenes of the form LL′BY (L = CAAC = cyclic alkyl(amino)carbene; L′ = NHC = N-heterocyclic carbene; Y = CN, NCS) coordinate to group 6 carbonyl complexes via the terminal donor of the pseudohalide substituent and undergo facile and fully reversible...

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Detalles Bibliográficos
Autores principales: Hagspiel, Stephan, Elezi, Dren, Arrowsmith, Merle, Fantuzzi, Felipe, Vargas, Alfredo, Rempel, Anna, Härterich, Marcel, Krummenacher, Ivo, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8188585/
https://www.ncbi.nlm.nih.gov/pubmed/34168848
http://dx.doi.org/10.1039/d1sc01580j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8188585/
https://www.ncbi.nlm.nih.gov/pubmed/34168848
http://dx.doi.org/10.1039/d1sc01580j

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