Asymmetric benzylic C(sp(3))−H acylation via dual nickel and photoredox catalysis

Asymmetric C(sp(3))−H functionalization is a persistent challenge in organic synthesis. Here, we report an asymmetric benzylic C−H acylation of alkylarenes employing carboxylic acids as acyl surrogates for the synthesis of α-aryl ketones via nickel and photoredox dual catalysis. This mild yet straig...

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Detalles Bibliográficos
Autores principales: Huan, Leitao, Shu, Xiaomin, Zu, Weisai, Zhong, De, Huo, Haohua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8192574/
https://www.ncbi.nlm.nih.gov/pubmed/34112783
http://dx.doi.org/10.1038/s41467-021-23887-2

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8192574/
https://www.ncbi.nlm.nih.gov/pubmed/34112783
http://dx.doi.org/10.1038/s41467-021-23887-2

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