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Asymmetric benzylic C(sp(3))−H acylation via dual nickel and photoredox catalysis
Asymmetric C(sp(3))−H functionalization is a persistent challenge in organic synthesis. Here, we report an asymmetric benzylic C−H acylation of alkylarenes employing carboxylic acids as acyl surrogates for the synthesis of α-aryl ketones via nickel and photoredox dual catalysis. This mild yet straig...
Autores principales: | Huan, Leitao, Shu, Xiaomin, Zu, Weisai, Zhong, De, Huo, Haohua |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8192574/ https://www.ncbi.nlm.nih.gov/pubmed/34112783 http://dx.doi.org/10.1038/s41467-021-23887-2 |
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