Selective Synthesis of Z-Silyl Enol Ethers via Ni-Catalyzed Remote Functionalization of Ketones

[Image: see text] We report a remote functionalization strategy, which allows the Z-selective synthesis of silyl enol ethers of (hetero)aromatic and aliphatic ketones via Ni-catalyzed chain walking from a distant olefin site. The positional selectivity is controlled by the directionality of the chai...

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Detalles Bibliográficos
Autores principales: Guven, Sinem, Kundu, Gourab, Weßels, Andrea, Ward, Jas S., Rissanen, Kari, Schoenebeck, Franziska
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8193638/
https://www.ncbi.nlm.nih.gov/pubmed/34033717
http://dx.doi.org/10.1021/jacs.1c01797

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8193638/
https://www.ncbi.nlm.nih.gov/pubmed/34033717
http://dx.doi.org/10.1021/jacs.1c01797

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