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Large Stabilization Effects by Intramolecular Beryllium Bonds in Ortho-Benzene Derivatives

Intramolecular interactions are shown to be key for favoring a given structure in systems with a variety of conformers. In ortho-substituted benzene derivatives including a beryllium moiety, beryllium bonds provide very large stabilizations with respect to non-bound conformers and enthalpy differenc...

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Detalles Bibliográficos
Autores principales: I-Ting, Tsai, Montero-Campillo, M. Merced, Alkorta, Ibon, Elguero, José, Yáñez, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8199991/
https://www.ncbi.nlm.nih.gov/pubmed/34199746
http://dx.doi.org/10.3390/molecules26113401