Reversal of Enantioselectivity in the Conjugate Addition Reaction of Cyclic Enones with the CuOTf/Azolium Catalytic System

Hydroxyamide-functionalized azolium salt (NHC•HI 4) was evaluated for dual enantioselective control in a Cu-catalyzed asymmetric conjugate addition (ACA) reaction. This investigation was based on our previously reported ACA reaction catalyzed using CuOTf combined with NHC•AgI complex 1. It was revea...

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Detalles Bibliográficos
Autores principales: Nakano, Yuki, Shimizu, Satoki, Takeda, Chihiro, Sakaguchi, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8200092/
https://www.ncbi.nlm.nih.gov/pubmed/34199812
http://dx.doi.org/10.3390/molecules26113404

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8200092/
https://www.ncbi.nlm.nih.gov/pubmed/34199812
http://dx.doi.org/10.3390/molecules26113404

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