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Tale of the Breslow intermediate, a central player in N-heterocyclic carbene organocatalysis: then and now

N-Heterocyclic carbenes (NHCs) belong to the popular family of organocatalysts used in a wide range of reactions, including that for the synthesis of complex natural products and biologically active compounds. In their organocatalytic manifestation, NHCs are known to impart umpolung reactivity to al...

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Detalles Bibliográficos
Autores principales: Pareek, Monika, Reddi, Yernaidu, Sunoj, Raghavan B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8208132/
https://www.ncbi.nlm.nih.gov/pubmed/34194690
http://dx.doi.org/10.1039/d1sc01910d