Cargando…

Manipulating valence and core electronic excitations of a transition-metal complex using UV/Vis and X-ray cavities

We demonstrate how optical cavities can be exploited to control both valence- and core-excitations in a prototypical model transition metal complex, ferricyanide ([Fe(iii)(CN)(6)](3−)), in an aqueous environment. The spectroscopic signatures of hybrid light-matter polariton states are revealed in UV...

Descripción completa

Detalles Bibliográficos
Autores principales: Gu, Bing, Cavaletto, Stefano M., Nascimento, Daniel R., Khalil, Munira, Govind, Niranjan, Mukamel, Shaul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8208133/
https://www.ncbi.nlm.nih.gov/pubmed/34194698
http://dx.doi.org/10.1039/d1sc01774h