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Transition-metal-like bonding behaviors of a boron atom in a boron-cluster boronyl complex [(η(7)-B(7))-B-BO](−)
Boron displays many unusual structural and bonding properties due to its electron deficiency. Here we show that a boron atom in a boron monoxide cluster (B(9)O(−)) exhibits transition-metal-like properties. Temperature-dependent photoelectron spectroscopy provided evidence of the existence of two is...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8208299/ https://www.ncbi.nlm.nih.gov/pubmed/34194706 http://dx.doi.org/10.1039/d1sc00534k |