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Unexpected formation of 1,2- and 1,4-bismethoxyl Sc(3)N@I(h)-C(80) derivatives via regioselective anion addition: an unambiguous structural identification and mechanism study

An attempt to achieve heterocyclic cycloadducts of Sc(3)N@I(h)-C(80)via reaction with Ph(2)C[double bond, length as m-dash]O, PhC[triple bond, length as m-dash]CPh or PhC[triple bond, length as m-dash]N in the presence of tetrabutylammonium hydroxide (TBAOH) stored in CH(3)OH led to the formation of...

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Detalles Bibliográficos
Autores principales: Hu, Yajing, Yao, Yang-Rong, Liu, Xuechen, Yu, Ao, Xie, Xiaoming, Abella, Laura, Rodríguez-Fortea, Antonio, Poblet, Josep M., Akasaka, Takeshi, Peng, Ping, Zhang, Qianyan, Xie, Su-Yuan, Li, Fang-Fang, Lu, Xing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8208303/
https://www.ncbi.nlm.nih.gov/pubmed/34194702
http://dx.doi.org/10.1039/d1sc01178b