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“Anti-electrostatic” halogen bonding in solution

Halogen-bonded (XB) complexes between halide anions and a cyclopropenylium-based anionic XB donor were characterized in solution for the first time. Spontaneous formation of such complexes confirms that halogen bonding is sufficiently strong to overcome electrostatic repulsion between two anions. Th...

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Detalles Bibliográficos
Autores principales: Loy, Cody, Holthoff, Jana M., Weiss, Robert, Huber, Stefan M., Rosokha, Sergiy V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8208320/
https://www.ncbi.nlm.nih.gov/pubmed/34194716
http://dx.doi.org/10.1039/d1sc01863a