Cargando…
“Anti-electrostatic” halogen bonding in solution
Halogen-bonded (XB) complexes between halide anions and a cyclopropenylium-based anionic XB donor were characterized in solution for the first time. Spontaneous formation of such complexes confirms that halogen bonding is sufficiently strong to overcome electrostatic repulsion between two anions. Th...
Autores principales: | Loy, Cody, Holthoff, Jana M., Weiss, Robert, Huber, Stefan M., Rosokha, Sergiy V. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8208320/ https://www.ncbi.nlm.nih.gov/pubmed/34194716 http://dx.doi.org/10.1039/d1sc01863a |
Ejemplares similares
-
“Anti‐electrostatic” Halogen Bonding between Ions of Like Charge
por: Holthoff, Jana M., et al.
Publicado: (2021) -
“Anti‐Electrostatic” Halogen Bonding
por: Holthoff, Jana M., et al.
Publicado: (2020) -
Examining a Transition from Supramolecular Halogen
Bonding to Covalent Bonds: Topological Analysis of Electron Densities
and Energies in the Complexes of Bromosubstituted Electrophiles
por: Miller, Daniel K., et al.
Publicado: (2021) -
Thermodynamics and Spectroscopy of Halogen- and Hydrogen-Bonded Complexes of Haloforms with Aromatic and Aliphatic Amines
por: Adeniyi, Emmanuel, et al.
Publicado: (2022) -
Exploring the supramolecular chemistry of cyclopropeniums: halogen-bonding-induced electrostatic assembly of polymers
por: Huang, Shiwen, et al.
Publicado: (2023)