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Zinc catalysed electrophilic C–H borylation of heteroarenes

Cationic zinc Lewis acids catalyse the C–H borylation of heteroarenes using pinacol borane (HBPin) or catechol borane (HBCat). An electrophile derived from [IDippZnEt][B(C(6)F(5))(4)] (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) combined with N,N-dimethyl-p-toluidine (DMT) proved the m...

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Detalles Bibliográficos
Autores principales: Grundy, Matthew E., Yuan, Kang, Nichol, Gary S., Ingleson, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8208323/
https://www.ncbi.nlm.nih.gov/pubmed/34194709
http://dx.doi.org/10.1039/d1sc01883c