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Enantioselective synthesis of tertiary boronic esters through catalytic asymmetric reversed hydroboration
Chiral tertiary boronic esters are important precursors to bioactive compounds and versatile synthetic intermediates to molecules containing quaternary stereocenters. The development of conjugate boryl addition to α,β-unsaturated amide has been hampered by the intrinsic low electrophilicity of the a...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8213697/ https://www.ncbi.nlm.nih.gov/pubmed/34145273 http://dx.doi.org/10.1038/s41467-021-24012-z |