Nickel-catalysed migratory hydroalkynylation and enantioselective hydroalkynylation of olefins with bromoalkynes

α-Chiral alkyne is a key structural element of many bioactive compounds, chemical probes, and functional materials, and is a valuable synthon in organic synthesis. Here we report a NiH-catalysed reductive migratory hydroalkynylation of olefins with bromoalkynes that delivers the corresponding benzyl...

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Detalles Bibliográficos
Autores principales: Jiang, Xiaoli, Han, Bo, Xue, Yuhang, Duan, Mei, Gui, Zhuofan, Wang, You, Zhu, Shaolin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8213830/
https://www.ncbi.nlm.nih.gov/pubmed/34145283
http://dx.doi.org/10.1038/s41467-021-24094-9

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8213830/
https://www.ncbi.nlm.nih.gov/pubmed/34145283
http://dx.doi.org/10.1038/s41467-021-24094-9

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