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Unsaturated Vinyl-Type Carbocation [(CH(3))(2)C=CH](+) in Its Carborane Salts

[Image: see text] The isobutylene carbocation (CH(3))(2)C=CH(+) was obtained in amorphous and crystalline salts with the carborane anion CHB(11)Cl(11)(–). The cation was characterized by X-ray crystallography and IR spectroscopy. Its crystal structure shows a relatively uniform ionic interaction of...

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Detalles Bibliográficos
Autores principales: Stoyanov, Evgenii S., Bagryanskaya, Irina Yu., Stoyanova, Irina V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8223440/
https://www.ncbi.nlm.nih.gov/pubmed/34179627
http://dx.doi.org/10.1021/acsomega.1c01297