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Sterics and Hydrogen Bonding Control Stereochemistry and Self-Sorting in BINOL-Based Assemblies

[Image: see text] Here we demonstrate how the hydrogen-bonding ability of a BINOL-based dialdehyde subcomponent dictated the stereochemical outcome of its subsequent self-assembly into one diastereomeric helicate form when bearing free hydroxy groups, and another in the case of its methylated congen...

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Detalles Bibliográficos
Autores principales: Zou, You-Quan, Zhang, Dawei, Ronson, Tanya K., Tarzia, Andrew, Lu, Zifei, Jelfs, Kim E., Nitschke, Jonathan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8227477/
https://www.ncbi.nlm.nih.gov/pubmed/34124891
http://dx.doi.org/10.1021/jacs.1c05172