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Thermodynamic Derivation of Scaling at the Liquid–Vapor Critical Point

With the use of thermodynamics and general equilibrium conditions only, we study the entropy of a fluid in the vicinity of the critical point of the liquid–vapor phase transition. By assuming a general form for the coexistence curve in the vicinity of the critical point, we show that the functional...

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Detalles Bibliográficos
Autores principales: Obeso-Jureidini, Juan Carlos, Olascoaga, Daniela, Romero-Rochín, Victor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8229170/
https://www.ncbi.nlm.nih.gov/pubmed/34198772
http://dx.doi.org/10.3390/e23060720