Nucleophilic Substitution at Tetracoordinate Phosphorus. Stereochemical Course and Mechanisms of Nucleophilic Displacement Reactions at Phosphorus in Diastereomeric cis- and trans-2-Halogeno-4-methyl-1,3,2-dioxaphosphorinan-2-thiones: Experimental and DFT Studies

Geometrical cis- and trans- isomers of 2-chloro-, 2-bromo- and 2-fluoro-4-methyl-1,3,2-dioxaphosphorinan-2-thiones were obtained in a diastereoselective way by (a) sulfurization of corresponding cyclic P(III)-halogenides, (b) reaction of cyclic phosphorothioic acids with phosphorus pentachloride and...

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Detalles Bibliográficos
Autores principales: Mikołajczyk, Marian, Ziemnicka, Barbara, Krzywański, Jan, Cypryk, Marek, Gostyński, Bartłomiej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8232685/
https://www.ncbi.nlm.nih.gov/pubmed/34203941
http://dx.doi.org/10.3390/molecules26123655

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8232685/
https://www.ncbi.nlm.nih.gov/pubmed/34203941
http://dx.doi.org/10.3390/molecules26123655

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