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Nucleophilic Substitution at Tetracoordinate Phosphorus. Stereochemical Course and Mechanisms of Nucleophilic Displacement Reactions at Phosphorus in Diastereomeric cis- and trans-2-Halogeno-4-methyl-1,3,2-dioxaphosphorinan-2-thiones: Experimental and DFT Studies
Geometrical cis- and trans- isomers of 2-chloro-, 2-bromo- and 2-fluoro-4-methyl-1,3,2-dioxaphosphorinan-2-thiones were obtained in a diastereoselective way by (a) sulfurization of corresponding cyclic P(III)-halogenides, (b) reaction of cyclic phosphorothioic acids with phosphorus pentachloride and...
Autores principales: | Mikołajczyk, Marian, Ziemnicka, Barbara, Krzywański, Jan, Cypryk, Marek, Gostyński, Bartłomiej |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8232685/ https://www.ncbi.nlm.nih.gov/pubmed/34203941 http://dx.doi.org/10.3390/molecules26123655 |
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