NbCl(5)-Mg Reagent System in Regio- and Stereoselective Synthesis of (2Z)-Alkenylamines and (3Z)-Alkenylols from Substituted 2-Alkynylamines and 3-Alkynylols

The reduction of N,N-disubstituted 2-alkynylamines and substituted 3-alkynylols using the NbCl(5)–Mg reagent system affords the corresponding dideuterated (2Z)-alkenylamine and (3Z)-alkenylol derivatives in high yields in a regio- and stereoselective manner through the deuterolysis (or hydrolysis)....

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Detalles Bibliográficos
Autores principales: Kadikova, Rita N., Gabdullin, Azat M., Mozgovoj, Oleg S., Ramazanov, Ilfir R., Dzhemilev, Usein M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8234592/
https://www.ncbi.nlm.nih.gov/pubmed/34207186
http://dx.doi.org/10.3390/molecules26123722

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8234592/
https://www.ncbi.nlm.nih.gov/pubmed/34207186
http://dx.doi.org/10.3390/molecules26123722

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