The Reaction of Hydrogen Halides with Tetrahydroborate Anion and Hexahydro-closo-hexaborate Dianion

The mechanism of the consecutive halogenation of the tetrahydroborate anion [BH(4)](−) by hydrogen halides (HX, X = F, Cl, Br) and hexahydro-closo-hexaborate dianion [B(6)H(6)](2−) by HCl via electrophile-induced nucleophilic substitution (EINS) was established by ab initio DFT calculations [M06/6-3...

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Detalles Bibliográficos
Autores principales: Golub, Igor E., Filippov, Oleg A., Belkova, Natalia V., Epstein, Lina M., Shubina, Elena S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8235096/
https://www.ncbi.nlm.nih.gov/pubmed/34202981
http://dx.doi.org/10.3390/molecules26123754

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8235096/
https://www.ncbi.nlm.nih.gov/pubmed/34202981
http://dx.doi.org/10.3390/molecules26123754

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