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The Reaction of Hydrogen Halides with Tetrahydroborate Anion and Hexahydro-closo-hexaborate Dianion
The mechanism of the consecutive halogenation of the tetrahydroborate anion [BH(4)](−) by hydrogen halides (HX, X = F, Cl, Br) and hexahydro-closo-hexaborate dianion [B(6)H(6)](2−) by HCl via electrophile-induced nucleophilic substitution (EINS) was established by ab initio DFT calculations [M06/6-3...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8235096/ https://www.ncbi.nlm.nih.gov/pubmed/34202981 http://dx.doi.org/10.3390/molecules26123754 |