Proton-coupled electron transfer reactivities of electronically divergent heme superoxide intermediates: a kinetic, thermodynamic, and theoretical study

Heme superoxides are one of the most versatile metallo-intermediates in biology, and they mediate a vast variety of oxidation and oxygenation reactions involving O(2(g)). Overall proton-coupled electron transfer (PCET) processes they facilitate may proceed via several different mechanistic pathways,...

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Detalles Bibliográficos
Autores principales: Mondal, Pritam, Ishigami, Izumi, Gérard, Emilie F., Lim, Chaeeun, Yeh, Syun-Ru, de Visser, Sam P., Wijeratne, Gayan B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8246096/
https://www.ncbi.nlm.nih.gov/pubmed/34257888
http://dx.doi.org/10.1039/d1sc01952j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8246096/
https://www.ncbi.nlm.nih.gov/pubmed/34257888
http://dx.doi.org/10.1039/d1sc01952j

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