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Proton-coupled electron transfer reactivities of electronically divergent heme superoxide intermediates: a kinetic, thermodynamic, and theoretical study
Heme superoxides are one of the most versatile metallo-intermediates in biology, and they mediate a vast variety of oxidation and oxygenation reactions involving O(2(g)). Overall proton-coupled electron transfer (PCET) processes they facilitate may proceed via several different mechanistic pathways,...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8246096/ https://www.ncbi.nlm.nih.gov/pubmed/34257888 http://dx.doi.org/10.1039/d1sc01952j |