Pressure-induced Jahn–Teller switch in the homoleptic hybrid perovskite [(CH(3))(2)NH(2)]Cu(HCOO)(3): orbital reordering by unconventional degrees of freedom

Through in situ, high-pressure X-ray diffraction experiments we have shown that the homoleptic perovskite-like coordination polymer [(CH(3))(2)NH(2)]Cu(HCOO)(3) undergoes a pressure-induced orbital reordering phase transition above 5.20 GPa. This transition is distinct from previously reported Jahn–...

Descripción completa

Detalles Bibliográficos
Autores principales: Scatena, Rebecca, Andrzejewski, Michał, Johnson, Roger D., Macchi, Piero
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8246535/
https://www.ncbi.nlm.nih.gov/pubmed/34277008
http://dx.doi.org/10.1039/d1tc01966j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8246535/
https://www.ncbi.nlm.nih.gov/pubmed/34277008
http://dx.doi.org/10.1039/d1tc01966j

Ejemplares similares