Stereoselective and Stereospecific Triflate‐Mediated Intramolecular Schmidt Reaction: Ready Access to Alkaloid Skeletons

The stereoselectivity and stereospecificity of the triflate‐mediated intramolecular Schmidt reaction of substituted 3‐(1‐azidocyclohexyl)propanol derivatives leading to octahydro‐1H‐pyrrolo[1,2‐a]azepine, the structural skeleton of several important families of alkaloids such as the Stemona alkaloid...

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Detalles Bibliográficos
Autores principales: Gnägi, Lars, Arnold, Remo, Giornal, Florence, Jangra, Harish, Kapat, Ajoy, Nyfeler, Erich, Schärer, Robin M., Zipse, Hendrik, Renaud, Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251548/
https://www.ncbi.nlm.nih.gov/pubmed/33594703
http://dx.doi.org/10.1002/anie.202016892

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8251548/
https://www.ncbi.nlm.nih.gov/pubmed/33594703
http://dx.doi.org/10.1002/anie.202016892

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